How It Works Residual chlorine in treated water has two major components, hypochlorous acid (HOCl) and hypochlorite ions (OCl). The quantity of each component in the sample is dependant upon the pH value of the water, the component of interest is the content of HOCl. At a pH of between 4 5 the free chlorine is nearly 100 % HOCl, whereas at a pH level of 10 11 the free chlorine is nearly 100 % OCl. It is recommended that a buffer system is used when the water sample needs to be stabilised. This enables the monitor to accurately measure the HOCl content at a lower pH level and ensuring repeatable accuracy. The Medway 2 buffer system can use either phosphate or acetic acid solutions. To measure total chlorine, potassium iodide is be added to the buffer solution. The Medway 2 also has the option for carbon dioxide (CO2), buffer addition.
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